학회 |
한국화학공학회 |
학술대회 |
2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터) |
권호 |
19권 1호, p.743 |
발표분야 |
재료 |
제목 |
Determination of Coprecipitation pH for Preparing the Nickel-Manganese-Cobalt Mixed hydroxides |
초록 |
Lithium nickel-manganese-cobalt oxides (LiNixMnyCo1-x-yO2) have been extensively studied as a promising cathode material for high-energy density lithium-ion battery systems. Lithium nickel-manganese-cobalt oxides synthesized by solid-state method often result in an inhomogeneous elemental distribution or the presence of impurity phase, leading to inferior electrochemical cycling performance. To obtain an ideal cathode material with high-capacity and high-performance, the use of a homogeneous precursor of mixed-hydroxides ((NixMnyCo1-x-y)(OH)2) is widely adopted. Coprecipitation processes often use ammonia water producing a plenty of nitrogen compounds that are characteristic of pungent smell and environmentally unfriendly. In this presentation, we report a novel non-ammonia coprecipitation method using a chelating agent and the method for calculration and determination of optimum pH condition for the preparation of homogeneous mixed-hydroxides. |
저자 |
김현진1, 남경모1, 송승완1, 강동현2, 김용석2
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소속 |
1충남대, 2Energy Material Tech |
키워드 |
lithium-ion battery; electrochemical
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E-Mail |
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