화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 봄 (04/29 ~ 05/01, BEXCO (부산))
권호 19권 1호
발표분야 고분자_포스터
제목 Electro-optical and Electrochemical Properties of an Ionic Polyacetylene Having a Bulky N-Benzoyl-2-ethynylpyridinium tetraphenylborate as Substituent
초록 The ion-exchange reaction of poly(N-benzoyl-2-ethynylpyridium chloride) using sodium tetraphenylborate yielded an ionic polyacetylene with a highly bulky N-benzoyl-2-ethynylpyridinium tetraphenylborate as substituent. The analytical data revealed that this polymer has a conjugated polymer backbone system having the designed substituents. The kinetics of the redox process of polymer was controlled by the diffusion process.  This polymer showed characteristic wide UV-visible absorption band and green PL maximum value at 620 nm.

 
저자 이지원1, 제갈영순2, 진성호3, 심상연4, 임권택5, 박종욱1
소속 1가톨릭대, 2경일대, 3부산대, 4강릉원주대, 5부경대
키워드 Polyacetylene; 2-ethynylpyridine; tetraphenylborate; cyclic voltammogram; photoluminescence
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