학회 |
한국공업화학회 |
학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
권호 |
19권 1호 |
발표분야 |
고분자_포스터 |
제목 |
Electro-optical and Electrochemical Properties of an Ionic Polyacetylene Having a Bulky N-Benzoyl-2-ethynylpyridinium tetraphenylborate as Substituent |
초록 |
The ion-exchange reaction of poly(N-benzoyl-2-ethynylpyridium chloride) using sodium tetraphenylborate yielded an ionic polyacetylene with a highly bulky N-benzoyl-2-ethynylpyridinium tetraphenylborate as substituent. The analytical data revealed that this polymer has a conjugated polymer backbone system having the designed substituents. The kinetics of the redox process of polymer was controlled by the diffusion process. This polymer showed characteristic wide UV-visible absorption band and green PL maximum value at 620 nm.
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저자 |
이지원1, 제갈영순2, 진성호3, 심상연4, 임권택5, 박종욱1
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소속 |
1가톨릭대, 2경일대, 3부산대, 4강릉원주대, 5부경대 |
키워드 |
Polyacetylene; 2-ethynylpyridine; tetraphenylborate; cyclic voltammogram; photoluminescence
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E-Mail |
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