| 학회 | 한국화학공학회 |
| 학술대회 | 2005년 봄 (04/22 ~ 04/23, 여수대학교) |
| 권호 | 11권 1호, p.78 |
| 발표분야 | 고분자 |
| 제목 | The Effect of Crosslinking with the Hydrophilic Group on Sulfonated Polyimide for Polymer Electrolyte Membrane Fuel Cell |
| 초록 | To investigate the effect of crosslinking by hydrophilic group on sulfonated polyimide electrolyte membrane, sulfonated polyimide end-capped with maleic anhydride was synthesized using 1,4,5,8-naphthalenetetracarboxylic dianhydride, 4,4’-diaminobiphenyl, 2,2’-disulfonic acid, 2-bis [4-(4-aminophenoxy)phenyl] hexafluropropane and maleic anhydride. The sulfonated polyimides end-capped with maleic anhydride were self-crosslinked or crosslinked with poly(ethylene glycol) diacrylate. A series of the crosslinked sulfonated polyimides having various ratio of sulfonated polyimide and poly(ethylene glycol) diacrylate were prepared and compared with uncrosslinked and self-crosslinked sulfonated polyimides. The synthesized sulfonated polyimide films were characterized for FT-IR spectrum, thermal stability, ion exchange capacity, water uptake, hydrolytic stability, morphological structure and proton conductivity. Acknowledgement This work was supported by the Ministry of Science and Technology of Korea through the National Research Laboratory Program. |
| 저자 | 김민주, 장원봉, Saimani Sundar, 설용건, 한학수 |
| 소속 | 연세대 |
| 키워드 | sulfonated polyimide; poly(ethylene glycol) diacrylate; crosslinking; polymer electrolyte membrane; fuel cell; proton conductivity |
| 원문파일 | 초록 보기 |
