| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
| 권호 |
21권 1호, p.484 |
| 발표분야 |
에너지 |
| 제목 |
The effect of Cu/Fe molar ratio on the catalytic performance over copper ferrite integrated with mesoporous alumina catalysts for high temperature water gas shift reaction |
| 초록 |
The copper ferrite integrated with mesoporous alumina catalysts have been applied for high temperature water gas shift reaction from waste-derived synthesis gas. The Cu/Fe molar ratio was systematically varied to optimize CuxFe(3-x)O4-MA catalysts (x = 0.5, 1.0, 1.5, 2.0, or 2.5). The copper ferrite catalyst prepared at the Cu/Fe molar ratio of 1 exhibited the highest CO conversion as well as 100 % selectivity to CO2 among prepared catalysts. The improved performance of the catalyst is attributed to the easier reducibility and formation of reduced form of the Cu-species. In addition, the optimized catalyst showed stable activity (XCO=78% at 450 oC) for 30 h even at a very high GHSV of 84,000 h-1. |
| 저자 |
김학민, 정대운, Ajay Jha, 심재오, 장원준, 전경원, 나현석, 이열림, 노현석
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| 소속 |
연세대 |
| 키워드 |
High temperature water gas shift; Cu/Fe molar ratio; Easier reducibility; Reduced Cu-species
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| E-Mail |
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| 원문파일 |
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