초록 |
Poly(3-hexylthiophene) (P3HT) is one of the conducting polymers having good electrical properties. Self-assembly of P3HT has been studied intensively because electrical properties of the P3HT were sensitive to their nanostructure. P3HT usually shows self-assembled nano-fibril morphology whereas the nature of amphiphilic polymers lets them self-assemble into various nanostructure. This phenomenon has been studied recently, but it is not yet well understood. Hydrophilic polymers containing oligo(ethylene glycol) methyl ether methacrylate (OEGMA) and 2-(2-methoxyethoxy)ethyl methacrylate (MEO2MA) are well known temperature responsive polymer showing good solubility, and lower critical solution temperature (LCST) in water. In this study, amphiphilic diblock copolymers having P3HT were synthesized. Details on synthetic method and thermoresponsive properties of the amphiphilic diblock copolymers in solution will be presented. |