화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 가을 (11/02 ~ 11/04, 경원대학교)
권호 15권 2호
발표분야 정보.전자소재
제목 Synthesis of an Ionic Conjugated Polymer from Propargylammonium Salt by Using Transition Metal Catalysts and Its Electro-Optical and Electrochemical Properties
초록 A new conjugated polymer with ammonium salts was synthesized and characterized. The polymerization of propargylammonium salt catalyzed by transition metal catalysts proceeded well to give high yield of polymer. The polymer structure was characterized by various instrumental methods to have a conjugated polymer backbone system having the designed substituents. This polymer was mostly soluble in organic solvents. The CVs ofpolymer exhibited the irreversible electrochemical behaviors between the doping and undoping peaks. It was found that the kinetics of the redox process of polymer might be controlled by the diffusion process from the experiment of the oxidation current density of polymer versus the scan rate.
저자 제갈영순1, 진성호2, 박종욱3, 심상연4, 임권택5
소속 1경일대, 2부산대, 3가톨릭대, 4강릉-원주대, 5부경대
키워드 Polyacetylene; conjugated polymer; ammonium salt; photoluminescence; cyclic voltammogram
E-Mail