| 학회 |
한국공업화학회 |
| 학술대회 |
2011년 가을 (11/02 ~ 11/04, 경원대학교) |
| 권호 |
15권 2호 |
| 발표분야 |
정보.전자소재 |
| 제목 |
Synthesis of a Polyacetylene with Thiophene Substituents and Its Electro-Optical and Electrochemical Properties |
| 초록 |
In this study,a polyacetylene having thiophene substituent was preparedfrom the polymerization of thienylacetylene by using various transition metalcatalysts. The chemical structure of polymer was characterized by various instrumental methods to have a polyacetylene polymer lackbone with thienyl substituents. The electro-optical and electrochemical properties of the resulting conjugated polymer were studied. The cyclovoltammograms of polymer exhibited the irreversible electrochemical behaviors between the doping and undoping peaks. The kinetics of the redox process of polymer was controlled by the diffusion process from the experiment plotting the oxidation current density of polymer versus the scan rate. |
| 저자 |
제갈영순1, 진성호2
|
| 소속 |
1경일대, 2부산대 |
| 키워드 |
Polyacetylene; Thiophene; Catalyst; Characterization; Photoluminescence
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| E-Mail |
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