| 학회 | 한국화학공학회 |
| 학술대회 | 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터) |
| 권호 | 16권 2호, p.2180 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Post-synthesis Treatment of Zn-tetrakis(4-carboxyphenyl) porphyrin framework using Copper solution and its Catalytic Properties |
| 초록 | The MOF (Metal-Organic Framework) has received great attention due to numerous applications such as gas separation, purification, chemical sensing, drug delivery, storage materials and catalysis through changing SBU (Secondary building unit) and post-synthesis treatment. Post-synthesis treatment includes introducing covalent attachment to the organic linker, grafting of organic molecules at metal sites coordinative vacancies created after solvent elimination and replacing the metal ion by suitable elements. Herein, we report facile post-synthesis treatment of MOF consisting of tetrakis(4-carboxyphenyl) porphyrin, 4,4’-bipyridine and zinc nitrate hexahydrate (Zn-TCPP-MOF)and its copper analog (Cu-TCPP-MOF). The catalytic properties of Cu-TCPP-MOF were studied over the ethylbenzene oxidation using tert-Butyl hydroperoxide as an oxidant. |
| 저자 | 이승엽1, Zuzana Musilov2, 정은영1, Ji ejka2, 박상언1 |
| 소속 | 1인하대, 2Heyrovsky institute of physical chemistry |
| 키워드 | porphyrin; Catalytic Properties |
| 원문파일 | 초록 보기 |
