| 학회 |
한국고분자학회 |
| 학술대회 |
2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO)) |
| 권호 |
45권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Alternating ring-opening copolymerization of epoxide and anhydride using a chromium complex with a sterically demanding amino triphenolate ligand |
| 초록 |
We have investigated alternating ring-opening copolymerization (ROCOP) of epoxides (limonene oxide, cyclohexene oxide) with anhydrides (phthalic anhydride, naphthalic anhydride and maleic anhydride) using a chromium complex containing sterically-demanding amino triphenolate ligand. The polymerization reactions were strongly affected by the type and the amount of co-catalyst, reaction time, and feed ratio of monomers. Under the optimized conditions, the chromium complex produced perfectly alternating polyesters with high molecular weights, high glass-transition temperatures, and low polydispersity. It also showed a very high activity (TOF up to 380 h −1 ). |
| 저자 |
유호균1, 배대영2, 임현기1, 이은성2, 손경선1
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| 소속 |
1충남대, 2포항공과대 |
| 키워드 |
Ring-opening copolymerization; chromium complex; amino triphenolate; epoxide; anhydride
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| E-Mail |
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