화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 고분자 구조 및 물성
제목 Characteristics and Reaction Kinetics of Solid-state Polymerization ofPoly(trimethylene terephthalate)
초록 Reaction kinetic model which is capable of describing the behaviors of solid-state polymerization of poly(trimethylene terephthalate)(PTT) has been developed. The solid-state polymerization of poly(trimethylene terephthalate)(PTT) has been carried out under reduced pressure at various temperatures ranging between 190℃ and 220℃. In solid-state polymerization, the overall reaction rate was governed by the reaction temperature and reaction atmosphere. The contents of carboxyl end group was decreased during solid-state polymerization with increasing reaction time. The melting temperature of solid-state polymerized PTT was higher at higher temperature of polymerization.
저자 김석훈, 홍원표, 김대섭, 김준호
소속 영남대
키워드 solid-state polymerization; PTT; poly(trimethylene terephthalate)
E-Mail