| 학회 |
한국공업화학회 |
| 학술대회 |
2014년 봄 (04/30 ~ 05/02, 제주국제컨벤션센터) |
| 권호 |
18권 1호 |
| 발표분야 |
미래산업형 기능성 고분자 재료의 제조 및 응용에 관한 첨단연구 동향 |
| 제목 |
Sulfonated poly(arylene ether ketone) electrolyte membranes fof fuel cell application |
| 초록 |
Composite membranes based on sulfonated poly(arylene ether ketone) (SPAEK) were fabricated by a solvent cast method. The brittleness of the SPAEK was compensated by introduction of organosiloxane polymer networks (OSPN). The sulfonated benzene silica mesoporous conductors (SMBS) maintain the water content at a high level, even at low relative humidity. Both OSPN and SMBS components enhance the proton conductivity of sPAEK membranes in a hydrated state, while maintaining the water uptake below 55% even at 100℃. The SAXS patterns of the composite membranes explain the water-related membrane properties of membranes. The maximum power of the composite membrane based membrane-electrode assembly (MEA) was much higher than that of a Nafion-based oneat low relative humidities of 70% and 45%,, due to the capillary condensation effect of SMBS. |
| 저자 |
김덕준 |
| 소속 |
성균관대 |
| 키워드 |
polymer; electrolyte; membrane; fuel cell
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| E-Mail |
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