학회 | 한국고분자학회 |
학술대회 | 2002년 가을 (10/11 ~ 10/12, 군산대학교) |
권호 | 27권 2호, p.221 |
발표분야 | 특별 심포지엄 |
제목 | Cyclic Olefin Copolymers Containing Imide ringsvia Ring-opening Metathesis Polymerization |
초록 | Ring-opening metathesis polymerization (ROMP) of tricyclic norborneneimide monomers, exo,exo-1,1a,4,4a,5,6,7,8-octahydro-1,4-methanonaphthalene-6,7-dicarboxylic cyclohexylimide and n-hexylimide, produced polymers with good thermal stability and transparency. In this study, tricyclic norborneneimide monomers were copolymerized with norbornene to control the physical properties of the copolymers. ROMP of the monomers was carried out with Grubbs' catalyst and the copolymers were hydrogenated to remove the unsaturated double bonds of the copolymers. Details of the polymerization and physical properties of the polymers will be presented. |
저자 | 임시경, 김상율 |
소속 | 한국과학기술원 화학과 분자과학사업단(BK21) & 기능성고분자연구센터 |
키워드 | norbornene; tricyclic norborneneimide; ROMP; copolymerization; transparency |