화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2004년 가을 (10/08 ~ 10/09, 경북대학교)
권호 29권 2호, p.710
발표분야 분자전자 부문위원회
제목 Synthesis of Poly(p-phenylenevinylene)s with Electron-Withdrawing Cyano Group for Polymeric Light-Emitting Diodes
초록 An electron-withdrawing group onto the arylene ring or the vinyl group of poly(p-phenylenevinylene)(PPV) had lower the HOMO and LUMO energies of polymer than others. We synthesized PPV with an electron-withdrawing cyano group on polymer backbone,poly[5-cyano-2-(4’-(3”,7”-dimethylocttyl)oxy)phenoxy-1,4-phenylenevinylene] (p-CNDMOP-PPV) via the Gilch polymerization. Those were obtained UV- and PL data (450 nm and 605 nm) lower than PPV. We investigated the effect of the electron-withdrawing group on physical and electrochemical properties of p-CNDMOP-PPV, as well as the performance of light-emitting diodes.
저자 구대성1, 서황운1, 신원석1, 진성호1, 제갈영순2
소속 1부산대, 2경일대
키워드 유기EL
E-Mail