학회 |
한국고분자학회 |
학술대회 |
2004년 가을 (10/08 ~ 10/09, 경북대학교) |
권호 |
29권 2호, p.710 |
발표분야 |
분자전자 부문위원회 |
제목 |
Synthesis of Poly(p-phenylenevinylene)s with Electron-Withdrawing Cyano Group for Polymeric Light-Emitting Diodes |
초록 |
An electron-withdrawing group onto the arylene ring or the vinyl group of poly(p-phenylenevinylene)(PPV) had lower the HOMO and LUMO energies of polymer than others. We synthesized PPV with an electron-withdrawing cyano group on polymer backbone,poly[5-cyano-2-(4’-(3”,7”-dimethylocttyl)oxy)phenoxy-1,4-phenylenevinylene] (p-CNDMOP-PPV) via the Gilch polymerization. Those were obtained UV- and PL data (450 nm and 605 nm) lower than PPV. We investigated the effect of the electron-withdrawing group on physical and electrochemical properties of p-CNDMOP-PPV, as well as the performance of light-emitting diodes. |
저자 |
구대성1, 서황운1, 신원석1, 진성호1, 제갈영순2
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소속 |
1부산대, 2경일대 |
키워드 |
유기EL |
E-Mail |
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