화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 분자전자 소재 및 소자 기술(분자전자 부문위원회)
제목 Organic bulkheterojunction photovaoltaics based on poly(3-hexylthiophene) and pyran-4-ylidene-2-cyanoacetate derivatives
초록 The effect of annealing and fullerene loading on poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-(6,6)C61(PCBM) based bulkheterojunction photovaoltaics(PV) have been investigated. The novel dyes, Pyran-4-ylidene-2-cyanoacetate derivatives(dye#) were synthesized and mixed with the P3HT and PCBM blend matrix or deposited on P3HT:PCBM(1:1 w.%) film for the fabrication of organic PV cells. The films were deposited via spin coating from solution and vacuum evaporation. The structures of the PV cells were ITO/PSS:PEDOT/P3HT:PCBM/Al(Structure I), ITO/PSS:PEDOT/P3HT:PCBM/dye#/Al (Structure Ⅱ), and ITO/PSS:PEDOT/P3HT:PCBM:dye#/Al electrode (StructureⅢ). Their opto-electronic properties also measured with current-voltage measurement system equipped with 1000W solar simulator with AM 1.5 filter as a light source. The power conversion ficiency has been improved through the use of new dyes and the change of the device structures.
저자 한은미1, 이성안1, 주기영1, 김성훈2
소속 1전남대, 2경북대
키워드 Organic photovaoltaics; bulkheterojunction; poly(3-hexylthiophene)
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