화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 기능성 고분자
제목 Enhancement of Photovoltaic Efficiency by Polystyrene based Co-adsorbent on the TiO2 Nanostructure in the Dye-Sensitized Solar Cells
초록 The charge recombination at the TiO2-electrolyte interface in the dye-sensitized solar cells is a major factor to determine the photovoltaic efficiency of DSSC. In this work, we introduced polystyrene containing COOH functional-group as a co-adsorbent on the TiO2 layer. The hydrophobic co-absorbent molecule is anchored to the surface of titanium dioxide semiconductor and can be the barrier to protect the interface between the triiodide of electrolyte and mesoporous TiO2 layer. And the electron recombination rate was reduced and open circuit voltage (Voc), short circuit current (Jsc) and power conversion efficiency (η) were markedly enhanced under 1 sun condition. The electron recombination rate was characterized by electrochemical impedance spectroscopy (EIS).
저자 정준혁1, 강용수1, 이용건2, 박수일1, 전라선1
소속 1한양대, 2서울대
키워드 DSSC
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