화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 석유화학·윤활유_포스터
제목 Effects of potassium content on the ordered mesoporous Fe2O3-ZrO2 bimetal oxides for CO and CO2 hydrogenation to hydrocarbons
초록 Fischer-Tropsch Synthesis (FTS) reaction is a key catalytic process to obtain a wide range of hydrocarbons from syngas containing carbon oxides (CO and CO2). Based on our previous researches, the ordered mesoporous Fe2O3-ZrO2 bimetal oxides at an optimal molar ratio of Zr/Fe at ~ 0.25 showed the highest activity by maintaining its original mesoporous structures. Generally, the potassium promoter has been reported to improve catalytic activity by increasing an active iron carbide formation. To find an optimal amount of potassium promoter, the amount of potassium promoter was studied from 0.5 to 10wt% on the Fe2O3-ZrO2 bimetal oxides. Furthermore, those catalysts was applied to conversion of syngas containing carbon dioxide (CO2).
저자 조재민, 배종욱
소속 성균관대
키워드 Fischer-Tropsch Synthesis; mesoporous Fe2O3; ZrO2 incorporation; potassium; syngas containing CO or CO2; selectivity
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