| 학회 | 한국고분자학회 |
| 학술대회 | 2003년 가을 (10/10 ~ 10/11, 부경대학교) |
| 권호 | 28권 2호, p.210 |
| 발표분야 | 고분자 합성 |
| 제목 | Synthesis of Carbazole Derivative and its Use in Anionic Copolymerization with styrene |
| 초록 | Poly(N-vinyl carbazole)(PVK) is well known as an electroluminescent substance. In this respect, N-ethyl-3-vinylcarbazole was obtained from the ‘Wittig reaction’ of phosphonium ylide with 9-ethyl-3-carbazolecaboxaldehyde. The resulting product was purified by column chromatography and recrystallization in absolute ethanol. Butyllithium-initiated (co)polymerization of the carbazole derivative with styrene was performed under high vacuum. The resulting polymers were characterized by 1H-NMR and SEC. In this presentation , We will discuss the reactivity ratios of styrene and the carbazole derivative in organolithium-initiated copolymerization. |
| 저자 | 최규진1, 박준형1, 이선배1, 김지희1, 김광웅1, 김정안1, 이명수2, 류한욱3, D. Y. Shin3 |
| 소속 | 1한국과학기술(연), 2연세대, 3율촌화학 |
| 키워드 | Carbazole |
