| 학회 | 한국화학공학회 |
| 학술대회 | 2005년 봄 (04/22 ~ 04/23, 여수대학교) |
| 권호 | 11권 1호, p.1028 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Catalytic Decomposition of SO3 using the Alumina and Titania Supported Catalysts in IS Cycle for the Thermochemical Hydrogen Production |
| 초록 | Hydrogen is an attractive energy carrier, which could replace the fossil fuels. One of the promising methods for hydrogen production is thermochemical water splitting using VHTR (very high temperature gas-cooled reactor) Recently, Iodine-Sulfur (IS) thermochemical process has been focused as a hydrogen production process with a great potential for industrialization. IS process is the continuous and closed cycle system consisting of three chemical step reactions; ⅰ) Bunsen reaction, ⅱ) HI decomposition, ⅲ) H2SO4 decomposition. SO3 decomposition is a step reaction to convert SO3 into SO2 and O2 using the heat from VHTR in IS cycle. In this work, we prepared Al2O3 (Fe/Al2O3, Ni/Al2O3 and Co/Al2O3) and TiO2 (Fe/TiO2, Ni/TiO2, and Co/TiO2) supported catalysts by an incipient wetness impregnation and a sol-gel method to develop a high performance catalyst in this reaction. Catalytic reaction was performed in the temperature range of 750-900℃ in a fixed bed reactor. |
| 저자 | 김태호1, 공경택2, 이병권2, 정광덕2, 김홍곤2, 이관영1, 전희영3, 신채호3 |
| 소속 | 1고려대, 2한국과학기술(연), 3충북대 |
| 키워드 | thermochemical; IS cycle; catalytic decomposition; SO3 |
| 원문파일 | 초록 보기 |
