화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터)
권호 17권 2호
발표분야 포스터-정보.전자소재
제목 Synthesis and Characterization of New Photo Cross-linkable TFB (an alternating copolymer of fluorene and triphenylamine) derivative
초록 In organic light-emitting diode (OLED) device fabrication processes, solution processing is actively discussed and studied to make the large-sized panels with low cost. In such solution-processable OLEDs, cross-linkable hole-transporting layer (HTL) is especially important to overcome difficulties of multi-layered structure.  In this study, we synthesized new photo cross-linkable TFB (an alternating copolymer of fluorene and triphenylamine) derivatives which can be applied to the HTL of solution-processable OLEDs. The chemical and physical properties of the monomers and the polymers were characterized by NMR, TGA, GPC, UV-vis. absorption spectroscopy, cyclic voltammetry and etc. The polymer films showed good solvent resistance after cross-linking. We fabricated organic light-emitting diodes (OLED) in ITO / PEDOT:PSS / HTL / 26DCzPPy : Ir(mppy)3 / TPBi / LiF / Al. The detailed results about OLED characteristics will be discussed in the presentation.
저자 이주원, 한현, 윤성철, 이창진, 이재민
소속 한국화학(연)
키워드 OLED; HTL; Cross-linking
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