화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 가을 (10/24 ~ 10/25, 한양대학교)
권호 9권 2호, p.2406
발표분야 에너지/환경
제목 The effect of the size of pore-forming additives on polymer electrolyte membrane fuel cell
초록 The influence of pore-size distribution of the diffusion layer on mass-transport problems of proton exchange membrane fuel cells(PEMFCs) is investigated using electrodes with hydrophobic diffusion layers for which the pore-size distribution is designed by pore-forming additive. It is confirmed that the pore-size distribution of the diffusion layer is a more critical parameter for mass-transport processes within the electrode and for cell performance characteristics than the total porosity itself.
This study focused on the differences of the performance according to the size of pore-forming additives. Pore-forming additives for PEMFCs are used to minimize the effect of polarization which causes the decrease of cell performance. Single-cell performance tests and ac impedance analyses indicate that the performance loss due to mass-transport limitations can be reduced by enlarging the macropore volume in the diffusion layer. Catalyst layer was prepared onto the gas diffusion layer using spraying method.
저자 이성우, 손동훈, 김홍석, 이한규, 이태희
소속 연세대
키워드 Pore-forming additives; Mass-transport; Diffusion layer; Pore-size distribution
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