| 학회 |
한국화학공학회 |
| 학술대회 |
2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터) |
| 권호 |
15권 1호, p.1073 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Methanol-to-Olefin conversion over H-STA-7and H-STA-14 SAPOmolecular sieves |
| 초록 |
The catalytic properties of cage-based, small-pore SAPO molecular sieves H-STA-7 (framework type SAV) and H-STA-14 (KFI) for the methanol-to-olefin conversion (MTO) at 350 oC are compared with those obtained from H-SAPO-34 (CHA), the most widely studied catalyst for this reaction. It was found that H-STA-7 shows comparable MTO activity and catalyst stability to SAPO-34, while H-STA-14 does not. The overall results of this study suggest that the uniformity in cage shape and size in small-pore molecular sieves is a critical factor governing the type of the accumulated aromatic hydrocarbon species, and hence their MTO activity and deactivation pattern. |
| 저자 |
박민범1, 민형기1, Maria Castro2, Paul A. Wright2, 홍석봉1
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| 소속 |
1포항공과대, 2Univ. of St. Andrews |
| 키워드 |
MTO; zeolite; STA-7; hydrocarbon pool mechanism
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| E-Mail |
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| 원문파일 |
초록 보기 |
