| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 |
20권 1호 |
| 발표분야 |
무기재료_포스터 |
| 제목 |
Design and Preparation of Chelated Fe(III)/Fe(II) Liguid Catalyst for Hydrogen Sulfide Removal |
| 초록 |
Liquid desulfurization catalyst formulation utilizing iron chelated complex was designed based on the thermodynamic solubility and the pE-pH diagram models, and new chelating system of Fe(III/II)-C6H8O7-H2O was derived. Through the theoretical consideration, it was found that the simple thermodynamic calculation is very helpful to optimize the H2S removal efficiency, catalyst stability, and catalyst regeneration condition. A combination of optimized influencing factors has resulted in a new chelating formulation consisted of Fe(III)-citrate complex solution with Fe ion concentration of 1.0 ~ 2.5 wt%, pH of 8.0 in phosphate buffer system. The desulfurization performance of Fe (III)/Fe (II) chelating agents was investigated on a simulated sulfur-containing industrial gas composed of H2S and N2 in a gas-lift reactor. Test results have revealed that the proposed iron-based desulfurization solution showed a high sulfur removal efficiency and extended catalyst stability. |
| 저자 |
이지호1, 임규식1, 황준식2, 김유득2, 한양수1
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| 소속 |
1(주)나노스페이스, 2(주)해림엔지니어링 |
| 키워드 |
Desulfurization; Catalyst; Chelating
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| E-Mail |
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