화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터)
권호 42권 2호
발표분야 고분자구조 및 물성
제목 Self-assembly of carborane-poly(ethylene glycol) complexex with different molecular weight at the air-water interface
초록 A carborane is a cluster compound, particularly having a large amount of 10B atoms with the highest neutron capture cross section among all light elements. This unique property makes it a potential candidate for boron neutron capture therapy (BNCT). However, it has low water solubility for the BNCT application. Therefore, polyethylene glycol (PEG) was used to get carboranes the higher solubility by connecting with each other. This research used four different molecular weights of PEG (Mwt. 6000, 5010, 3800, 500). Its Langmuir-Blodgett (LB) films were investigated by using surface pressure area isotherm, atomic force microscope (AFM). The Isotherms show that carborane-PEG has different limiting area by the molecular weight. AFM images also show the close-packed arrangement for the higher concentration of PEG. Carborane-PEGs make small domains, ~ 0.011μm2 at the low pressure. As the surface pressure increases, the domains are aggregated and make larger domains, ~ 0.18μm2.
저자 장은석, 손대원
소속 한양대
키워드 Carborane; PEG; Langmuir-blodgett
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