초록 |
Using a 1-anthracen-9-yl-pyrene (AP) dual-core emitter, two new emitters of blue light, 1-spiro-9,90-bifluoren-4-yl-6-(10-spiro-9,90-bifluoren-4-yl-anthracen-9-yl)-pyrene (DSF-AP) and 1-[2-(9H-carbazol9-yl)phenyl]-6-[2-(9H-carbazol-9-yl)phenyl-anthracen-9-yl]-pyrene (DCP-AP), were synthesized. These two materials exhibited PLmax values at 443 nm and 448 nm in a chloroform solution, and at 458 nm and 463 nm in a thin-film state. Compared with the device made using an AP core lacking side groups, the device made with DCP-AP displayed 31% higher luminance efficiency (resulting in a value of 4.37 cd/A) and 32% higher power efficiency (to yield 1.93 lm/W), as well as a high external quantum efficiency(3.64%). |