| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis of Well definedAmphiphilicDiblockOligomers by Organotellurium-mediated living radical polymerization (TERP) |
| 초록 |
Organotellurium-mediated living radical polymerizations (TERPs) provide well-defined polymers with a variety of polar functional groups via degenerative chain-transfer polymerization. The high controllability of these polymerizations can be attributed to the rapid degenerative-transfer process between the polymer-end radicals and corresponding dormant species. The versatility of the methods allows the synthesis of AB diblock, ABA triblock, and ABC triblock copolymers by the successive addition of different monomers.The present work concerns design and well defined synthesis of polystyrene-b-poly(2-vinylpyridine) (PS-b-P2VP) and (P2VP-b-PS) an amphiphilic diblock copolymer for the first time via TERP. |
| 저자 |
산토쉬 쿠마르, 신원정, 이재석
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| 소속 |
광주과학기술원 |
| 키워드 |
amphiphilic; block copolymer; controlled radical polymerization; organotellurium-mediated living radical polymerization(TERP); oligomers
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| E-Mail |
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