화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.2029
발표분야 촉매 및 반응공학 (Catalysis and Reaction Engineering)
제목 Methanol Synthesis over the Mg modified Cu/ZnO/Al2O3 Catalysts via different preparation methods
초록 The objective of this research is to investigate the effect of Mg on the performance of Cu/Zn/MgO/Al2O3 catalysts, which made by a variety of methods. In this research, the methanol synthesis reaction over Mg promoted Cu/ZnO/ Al2O3 catalysts prepared via co-precipitation, impregnation and Sol-Gel method. The prepared catalysts were characterized by N2 adsorption, XRD, TPR, N2 Pulse technologies. The methanol synthesis reaction was carried out at T = 240 °C, P = 50 bar, GHSV = 4,000 h-1 and H2/CO = 2 in a fixed bed reactor. The Cu dispersion and surface area of the Mg modified catalysts were improved with the addition of Mg than Cu/ZnO/Al2O3 catalysts. Mg modified Cu/ZnO/M/Al2O3 catalyst show lower MeOH yield than Cu/ZnO/Al2O3 but higher stability than Cu/ZnO/Al2O3 catalyst.
저자 송현태1, 노영수2, 김현동1, Nasim Ghaffari Saeidabad1, Ali Alizadeh Eslami1, 문동주1
소속 1KIST, 2KIST / 고려대
키워드 촉매
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