학회 |
한국화학공학회 |
학술대회 |
2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터) |
권호 |
25권 2호, p.2029 |
발표분야 |
촉매 및 반응공학 (Catalysis and Reaction Engineering) |
제목 |
Methanol Synthesis over the Mg modified Cu/ZnO/Al2O3 Catalysts via different preparation methods |
초록 |
The objective of this research is to investigate the effect of Mg on the performance of Cu/Zn/MgO/Al2O3 catalysts, which made by a variety of methods. In this research, the methanol synthesis reaction over Mg promoted Cu/ZnO/ Al2O3 catalysts prepared via co-precipitation, impregnation and Sol-Gel method. The prepared catalysts were characterized by N2 adsorption, XRD, TPR, N2 Pulse technologies. The methanol synthesis reaction was carried out at T = 240 °C, P = 50 bar, GHSV = 4,000 h-1 and H2/CO = 2 in a fixed bed reactor. The Cu dispersion and surface area of the Mg modified catalysts were improved with the addition of Mg than Cu/ZnO/Al2O3 catalysts. Mg modified Cu/ZnO/M/Al2O3 catalyst show lower MeOH yield than Cu/ZnO/Al2O3 but higher stability than Cu/ZnO/Al2O3 catalyst. |
저자 |
송현태1, 노영수2, 김현동1, Nasim Ghaffari Saeidabad1, Ali Alizadeh Eslami1, 문동주1
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소속 |
1KIST, 2KIST / 고려대 |
키워드 |
촉매 |
E-Mail |
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원문파일 |
초록 보기 |