화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 봄 (05/01 ~ 05/03, ICC JEJU)
권호 17권 1호
발표분야 포스터-정보전자소재
제목 Synthesis of aromatic conjugated polymers containing fluorescent compounds as pendant
초록 ABSTRACT: The objective of this study is a synthesis of blue light material which has thermal stability, long life and excellent luminous efficiency. we synthesized a monomer type of Phenylethylene containing carbazole. and synthesized co-monomer containing octyl group to improve solubility. we conducted suzuki coupling polymerization with different concentrations. polymers are compared with polymerization properties, thermal stability and optical properties used GPC, UV-vis, PL spectrophotometer. polymers have 1543~3016 of molecular weight and 1.04~1.30 of PDI value. UV-vis absorption wavelengths showed 301nm~303nm and PL maximum emission wavelengths showed 480nm~489nm. relative quantum yield used 9,10-diphenylanthracene showed the maximum 25.8%.
저자 김우연1, 이승리1, 박병식2, 윤근병1
소속 1경북대, 2한국국제대
키워드 Keyword: Fluorescent polymer; Conjugated polymer; suzuki coupling; Phenylethylene; Quantum yield
E-Mail