학회 |
한국화학공학회 |
학술대회 |
2002년 가을 (10/24 ~ 10/26, 서울대학교) |
권호 |
8권 2호, p.3273 |
발표분야 |
열역학 |
제목 |
흡수식 냉동기에 사용되는 이온성 액체의 작동유체로서의 응용 |
초록 |
We first report application of ionic liquids to working fluids used in an absorption chiller. [bmim][BF4]+TFE and [bmim][Br]+TFE mixtures were chosen as a potential working fluids to overcome serious disadvantages of the conventional working fluids. Vapor pressures were measured by using the boiling point method in the concentration range of 40 to 90 ionic liquid mass percent and correlated with an Antoine equation. Heat capacity measurements of each pure ionic liquid were carried out in the temperature range of 293.15 to 323.15K and correlated with an simple polynomial equation. Resonable agreements were obtained between calculated and experimental values. Br anion was found to be better than BF4 in the aspect of the affinity with TFE |
저자 |
김기섭, 이 흔
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소속 |
한국과학기술원 생명화학공학과 |
키워드 |
vapor pressure; heat capacity; ionic liquid; absorption heat pump; TFE; bmim bf4; bmim br
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