| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Structural Estimation of Particle Arrays at Air-Water Interface Based on Silica Particles with Well-Defined and Highly-Grafted PMMA |
| 초록 |
Particle arrays at air-water interface based on silica nanoparticles with well-defined, highly-grafted dense poly(methyl methacrylate) (PMMA) were investigated. The surface-initiated activators regenerated by electron transfer for atom transfer radical polymerization (ARGET ATRP) of MMA mediated by a cooper complex was carried out with an initiator-fixed silica particle under atmosphere. The polymerization proceeded in a living manner in CuCl2/PMDETA system, and then silica nanoparticles with well-defined and highly-grafted PMMA were obtained. Monolayer of silica nanoparticles was formed at the air-water interface by Langmuir-Blodgett (LB) technique. Multi-layers of the particles were fabricated by repetition of the LB depositing. The particle arrays were estimated by measurement of scanning electron microscope (SEM) and surface pressure-area (π-A) isotherms. |
| 저자 |
문정민, 이장우
|
| 소속 |
부산대 |
| 키워드 |
polymer-grafted silica particles; ARGET ATRP; particle array; air-water interface surface; pressure-area isotherm
|
| E-Mail |
|
