| 학회 |
한국화학공학회 |
| 학술대회 |
2018년 봄 (04/25 ~ 04/27, 창원컨벤션센터) |
| 권호 |
24권 1호, p.518 |
| 발표분야 |
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| 제목 |
Mediated degradation of cinnamyl chloride by electrochemically generated Co(I)(bipyridine) in aqueous CTAB solutions |
| 초록 |
Cinnamyl chloride (one of the allyl chloride derivative) is one of the prominent environmental pollutant. This work reports cinnamyl chloride degradation by electrogenerated [Co(I)(bpy)3]+ (where bpy = 2,2’-bipyridine) electron mediator in environmentally benign CTAB aqueous solutions and examine the effects of phenyl substitution on the electrocatalytic degradation reaction. Cyclic voltammetry over a range of scan rates and cinnamyl chloride concentrations identified the rate limiting mechanism for Co(I)-catalyzed cinnamyl chloride degradation, which is compared with allyl chloride degradation for the phenyl substitution effect. |
| 저자 |
G. Muthuraman, K. Chandrasekara Pillai, 문일식
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| 소속 |
순천대 |
| 키워드 |
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| E-Mail |
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| 원문파일 |
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