| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of PEO-Based Block Copolymer by Controlled Radical Polymerization Techniques |
| 초록 |
Poly(ethylene oxide) (PEO) basd amphiphilic block copolymers has attracted attention due to the phase separation behavior. The amphiphilic block copolymers with different molecular weights can be used as a wide variety of materials with nanoscale structures such as biomaterials and mesoporous carbons by controlling its blocks length. Controlled radical polymerization could be good choice th prepare such amphiphilic block copolymers. In this work, PEO-based block copolymers were synthesized via ATRP (Atom transfer radical polymerization) and RAFT (Reversible addition fragmentation chain transfer) polymerization. ATRP was used to prepare polystyrene block copolymers with PEO, and RAFT process was used fr the synthesis of polyacrylonitrile block copolymer. The effect of the polymerization conditions will be descussed. |
| 저자 |
김태영1, 조아라1, 심소희1, 곽영제1, 김승현2
|
| 소속 |
1숭실대, 2인하대 |
| 키워드 |
ATRP; RAFT; block copolymer
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| E-Mail |
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