학회 |
한국화학공학회 |
학술대회 |
2007년 가을 (10/26 ~ 10/27, 한국과학기술원) |
권호 |
13권 2호, p.1650 |
발표분야 |
분리기술 |
제목 |
Recovery of Diluted Ionic Liquid in Water Using Ion Exchange Chromatography |
초록 |
In these days, ionic liquids had newly arisen in chemical engineering as functional substances, and it is potentially possible to apply these ionic liquids to other science and engineering areas. However it several drawbacks; ionic liquids are relatively expensive as compared with the conventional solvents and it is difficult to perfectly recover used ionic liquid for reuse. Usually, ionic liquids, which used in chemical process, remained in diluted water solution and were decomposed to the cationic and anionic forms. The purpose of this study is to purely recover ionic liquid from diluted ionic liquid–water mixture by the displacement ion exchange chromatography base on the physical properties of ionic liquids. [Bmim][BF4] aqueous solution was used as a model ionic liquid–water mixture system and recovery of [Bmim][BF4] had performed with several kinds of mobile-phase systems. Results of recovery of [Bmim][BF4] were confirmed by the UV spectroscopy and the mass spectrometry. |
저자 |
김일용1, 김진일1, 이주원2, 김정근2, 구윤모1
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소속 |
1인하대, 2ERC 초정밀분리기술연구센터 |
키워드 |
ionic liquid; recovery; chromatography; separation
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E-Mail |
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원문파일 |
초록 보기 |