화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2014년 봄 (04/30 ~ 05/02, 제주국제컨벤션센터)
권호 18권 1호
발표분야 포스터-고분자
제목 Novel carbazole-based light emitting copolymer containing (diphenylene)vinylene pendants: synthesis, characterization and their PLED application
초록 Light emitting polymers have been extensively studied due to practical applications of full color flat panel displays. The objective of this study is a synthesis of blue light material which has thermal stability, long life and excellent luminous efficiency. Monomer was synthesized by (diphenylene)vinylene and carbazole. Comonomer was synthesized by n-bromooctane and carbazole to improve solubility. The obtained polymers have 16000∼30000 of molecular weight and 1.1∼1.3 of PDI value. UV-vis absorption wavelengths showed 340nm at THF solution and maximum emission wavelengths of photoluminescence showed 450nm at THF solution. The values of quantum efficiency for P2∼P4 are determined to be 25.8%, 5.0%, and 3.5%, respectively. The results indicate that the quantum efficiency increases after incorporating (diphenylene)vinylene into the polymers.
저자 이승리, 박민정, 윤근병
소속 경북대
키워드 carbazole copolymer; blue light-emitting
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