화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 가을 (10/23 ~ 10/25, 대구 EXCO)
권호 19권 2호, p.1766
발표분야 열역학
제목 Vapor-liquid equilibria for the binary system of Acetonitrile + 1-hexyl-3-methylimidazoliumiodide at various temperatures from 283.15K to 333.15K
초록 Ionic liquids have gained much attention due to its unique chemical and physical properties, such as a high polarity, low melting pressure, non-volatility, and high thermal stability. These characteristics of ionic liquids give itself chance to be utilized in many applications, for example, dye sensitized solar cells(DSSCs) and supercapacitors. In this study, vapor-liquid equilibria (VLE) for the acetonitrile + 1-hexyl-3-methylimidazoliumiodide (HMImI) system were measured for six isotherms ranging from 283.15K to 333.15K at 10K intervals. The experimental data have been correlated with Peng-Robinson (PR) equation of state using Wong-Sandler mixing rule and NRTL model. The correlation results by Peng-Robinson equation of state with Wong-Sandler mixing rule and NRTL model are in reasonable agreement with the experimental data.
저자 임태현, 김병헌, 김화용
소속 서울대
키워드 Ionic liquid; VLE; acetonitrile; DSSC
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