화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 가을 (10/23 ~ 10/25, 대구 EXCO)
권호 19권 2호, p.1779
발표분야 열역학
제목 Measurement of isothermal VLE data for binary systems containing methyl iodide at various temperatures from 283.15 to 323.15 K
초록 VLE data for binary systems of dimethyl ether(DME)+methyl iodide(CH3I) and carbon dioxide(CO2)+methyl iodide(CH3I)  were measured at five equal spaced  temperatures between 283.15-323.15K using a circulation-type equilibrium apparatus. The experimental data were correlated with the Peng-Robinson equation of state (PR-EoS) using the Wong-Sandler (W-S) mixing rule, which was combined with the nonrandom two-liquid (NRTL) excess Gibbs free energy model and Peng-Robinson equation of state (PR-EoS) using the Universal mixing rule (UMR) as well as with the UNIQUAC model. Calculated results with these equations have given satisfactory results in the comparison with the experimental data.
저자 조 현, 김지은, 홍문현, 임종성
소속 서강대
키워드 VLE; PR-EoS; carbon dioxide; dimethyl ether; methyl iodide
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