학회 |
한국화학공학회 |
학술대회 |
2013년 가을 (10/23 ~ 10/25, 대구 EXCO) |
권호 |
19권 2호, p.1779 |
발표분야 |
열역학 |
제목 |
Measurement of isothermal VLE data for binary systems containing methyl iodide at various temperatures from 283.15 to 323.15 K |
초록 |
VLE data for binary systems of dimethyl ether(DME)+methyl iodide(CH3I) and carbon dioxide(CO2)+methyl iodide(CH3I) were measured at five equal spaced temperatures between 283.15-323.15K using a circulation-type equilibrium apparatus. The experimental data were correlated with the Peng-Robinson equation of state (PR-EoS) using the Wong-Sandler (W-S) mixing rule, which was combined with the nonrandom two-liquid (NRTL) excess Gibbs free energy model and Peng-Robinson equation of state (PR-EoS) using the Universal mixing rule (UMR) as well as with the UNIQUAC model. Calculated results with these equations have given satisfactory results in the comparison with the experimental data. |
저자 |
조 현, 김지은, 홍문현, 임종성
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소속 |
서강대 |
키워드 |
VLE; PR-EoS; carbon dioxide; dimethyl ether; methyl iodide
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E-Mail |
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원문파일 |
초록 보기 |