초록 |
The growing concern of the depletion of fossil fuel reserves and increasing energy demands have encouraged the exploration of new process develoment for converting biomass into valuable chemicals and renewable fuel components. From this point of veiw, we have recentry developed the synthetic process of the adipic acid which is one of the most important dicarboxylic acid, annually produced about 2.5 bilion kilograms and mainly used for the monomerof nylon from the most abundant monosaccharide galctose. To remove rech oxygen contents, we applied DODH reaction, rhenium catalyzed reduction, and it was successfully appied to afford the desired product with good efficiency. Especiallly, here in we would like to report DODH reaction with heterogeneous aluminium supported rhenium catalyst which intended to esay seperation and recycle. |