학회 | 한국화학공학회 |
학술대회 | 2008년 봄 (04/23 ~ 04/25, 제주ICC) |
권호 | 14권 1호, p.570 |
발표분야 | 에너지/환경 |
제목 | NOx reduction kinetic model for urea-basedSCR-SNCR hybrid processes |
초록 | For the hybrid process of homogeneous gas-phase SNCR (selective non-catalytic reduction) followed by SCR (selective catalytic reduction), a nitrogen oxides (NOx) reduction kinetic model is developed and validated with the data obtained from a pilot-scale urea-based SNCR-SCR reactor installed with a 150MW LPG burner. The SNCR kinetic mechanism with seven reactions for NOx reduction by urea-water solution is used to predict NOx reduction, ammonia slip and N2O concentration. The SCR kinetics on a commercial catalyst (TiO2-WO3-V2O5) is identified at temperature 200-400oC in the presence of oxygen (12%), where the Langmuir-Hinshelwood reaction mechanism is used. |
저자 | 임영일1, Thanh D.B. Nguyen1, 김성준2, 엄원현2, 유경선2 |
소속 | 1한경대, 2광운대 |
키워드 | NOx reduction; SCR (selective catalytic reduction); SNCR (selective non-catalytic reduction); Kinetic model; Urea solution |
VOD | VOD 보기 |
원문파일 | 초록 보기 |