화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 봄 (04/23 ~ 04/25, 제주ICC)
권호 14권 1호, p.570
발표분야 에너지/환경
제목 NOx reduction kinetic model for urea-basedSCR-SNCR hybrid processes
초록 For the hybrid process of homogeneous gas-phase SNCR (selective non-catalytic reduction) followed by SCR (selective catalytic reduction), a nitrogen oxides (NOx) reduction kinetic model is developed and validated with the data obtained from a pilot-scale urea-based SNCR-SCR reactor installed with a 150MW LPG burner.
The SNCR kinetic mechanism with seven reactions for NOx reduction by urea-water solution is used to predict NOx reduction, ammonia slip and N2O concentration. The SCR kinetics on a commercial catalyst (TiO2-WO3-V2O5) is identified at temperature 200-400oC in the presence of oxygen (12%), where the Langmuir-Hinshelwood reaction mechanism is used.
저자 임영일1, Thanh D.B. Nguyen1, 김성준2, 엄원현2, 유경선2
소속 1한경대, 2광운대
키워드 NOx reduction; SCR (selective catalytic reduction); SNCR (selective non-catalytic reduction); Kinetic model; Urea solution
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