화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO))
권호 25권 2호
발표분야 포스터-환경·에너지
제목 Photocatalytic activity in visible light of TiO2 with carbon-fluorine introduced by Plasma
초록 In this paper, CF4 plasma surface treatment is performed on commercial TiO2 to improve a photocatalytic efficiency. The photodegradation efficiency of TiO2 is significantly increased from 50.2% to 82.1% in 120 min via CF4 plasma treatment of TiO2. In addition, TiO2 treated with CF4 plasma exhibits a photodegradation rate constant of 0.0150 min-1, which is 2.6 times higher than that of TiO2 (0.0057 min-1). It is, thus, determined that CF4 plasma treatment effectively improves the photocatalytic effect of TiO2. It is attributed to the increase of oxygen vacancies by the introduction of heterogeneous elements of C and F atoms into TiO2 using CF4 plasma treatment. In addition, the F- ion species physically adsorbed on the TiO2 surface promotes the formation of hydroxy free radicals, so that the decomposition of rhodamine B occurs effectively.
저자 이란은, 이혜련, 임채훈, 김대섭, 김석진, 정서경, 이영석
소속 충남대
키워드 Titanium dioxide; Fluorination; Rhodamine B; CF4 Plasma
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