화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 우수논문(구두)_박사과정
제목 Surprising Antioxidation Activity of Transition Metal Dichalcogenide Nanosheets
초록 Two-dimensional transition metal dichalcogenides (TMDs) endowed with an ultrathin layer represent specific optical characteristics due to their large surface area as well as intrinsic band structure. Taking advantages of these structural and optical properties, herein we propose novel TMD-based antioxidation platform, in which TMD nanosheets, including MoS2, WS2, MoSe2, and WSe2, are finely dispersed in water with aids of amphiphilic poly (ε-caprolactone)-b-poly (ethylene oxide) copolymer. We figure out that the TMD nanosheets indeed show extraordinary enhanced and prolonged radical scavenging performance irrelevant to storage conditions. Modeling study elucidates that this excellent antioxidation activity is originated from the favored hydrogen atom dissociation via the defective TMD nanosheet in aqueous media.
저자 김지은, 김진웅
소속 한양대
키워드 TMDs; amphiphilic copolymer; radical scavenging; antioxidation
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