화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터)
권호 19권 1호, p.74
발표분야 고분자
제목 Efficient Synthesis of Water-dispersible Conducting Polypyrrole Nanoparticles
초록 Among the conducting polymers, polpyrrole(PPy) has attracted great attention because of its high electrical conductivity and good environmental stability. PPy has been considered as the key material to many potential applications. In this study, PPy nanoparticles were prepared using poly(styrene sulfonate) (PSS) as a polymeric surfactant by in-situ doping oxidative polymerization [1] in acidic medium. PSS formed aggregates like a stabilizer of emulsion system in acidic medium. The species and concentration of acid and oxidant have been carefully investigated to optimize the polymerization, conjugated structure, size, and conductivity of the PPy nanoparticles. The particle size of PPy nanoparticles was adjusted by concentration of acid [2]. Conducting thin film based on PPy nanoparticles was prepared on glass. After coating process, conducting properties were characterized by 4-probe meter. PPy nanoparticles can be applying to electrical devices such as capacitors, electrostatic discharge, solar cell, OLED and transistor.
저자 이승환, 이선종, 류현욱, 박홍관, 유도혁, 김용석, 김중현
소속 연세대
키워드 Polypyrrole nanoparticles; binary mixture acid; doping; electrical properties; counter-ion
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