| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터) |
| 권호 |
40권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Micellar and vesicular nanoassemblies of triazole-based amphiphilic probes triggered by mercury(ll) ions in a 100% aqueous medium |
| 초록 |
Amphiphilic molecules based on triazole-based aromatic segment and hydrophilic tri(ethylene oxide) were easily synthesized using facile Click chemistry which act as a fluorescent turn-off Hg2+-chemoprobe in an aqueous solution. Interestingly, it revealed that the metal-binding process of amphiphiles can induce the nano-assemblies even below the CMCs, and the binding stoichiometry affects the morphologies of the resultant nanostructures. The self-assembling behaviour of the amphiphiles was examined by UV-Vis and fluorescence spectroscopy. The formation of nano-aggregates was confirmed by TEM and DLS. Additionally, 1H-NMR and FT-IR experiments show the Hg2+-binding mechanism and the evidence for the triazole-based amphiphile-Hg2+ complexes. The metal-amphiphile conjugates provide a useful and simple strategy for the detection of toxic heavy metal ions in aqueous medium. |
| 저자 |
김인혜1, 정유정1, 조병기2, 이은지1
|
| 소속 |
1충남대, 2단국대 |
| 키워드 |
self-assembly; amphiphilc molecule; Click chemistry; mercury ion; nanostructures
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| E-Mail |
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