| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 봄 (04/07 ~ 04/09, 대전컨벤션센터) |
| 권호 |
46권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis and Characterization of All-Solid-State Polymer Electrolytes Based on Anion-Trapping Boron Moieties and Polysiloxane for Lithium Metal Batteries |
| 초록 |
In this study, all-solid-state polymer electrolytes were prepared via thiol-ene click reaction between anion-trapping boron moieties and polysiloxane. Boron containing poly(ethylene glycol) (PEG) crosslinker was synthesized by the reaction between trimethyl borate and poly(ethylene glycol) methacrylate. Branched polysiloxane with thiol group was synthesized by acid-catalyzed reaction between (3-mercaptopropyl)dimethoxymethylsilane and (3-mercaptopropyl)trimethylsilane. Allyl PEG was synthesized by reaction between poly(ethylene glycol) methyl ether and allyl bromide using KOH catalyst. The all-solid-state polymer electrolytes were prepared by UV-initiated thiol-ene click reaction between carbon-carbon double bond of allyl PEG and the boron crosslinker and thiol group of polysiloxane. The thermal properties and ionic conductivity of the prepared solid polymer electrolytes were investigated. |
| 저자 |
홍동기1, 백지훈2, 김상완1, 이종찬1
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| 소속 |
1서울대, 2한국화학(연) |
| 키워드 |
Solid Polymer Electrolytes; Anion-Trapping; Lithium Ion Batteries; Polysiloxane; Thiol-ene Click Reaction
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| E-Mail |
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