| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Crosslinkable polyimide with allyl side chain. |
| 초록 |
Recently, there is a development of plastic substrates which are replaced with glass substrates as display substrates and polyimide is one of candidate of flexible substrate. There are many researches for introduction of fluorine moiety, ether linkage or alicyclic structure for reveal colorless property of polyimide by disturbing charge transfer complex formation. But they have drawbacks such as poor chemical resistance and high thermal expansion property. In this study, we investigated polyimide having double bond as cross-linker for reducing CTE value and improving chemical resistance. We prepared polyimide with 6-FDA as the anhydride monomer and diamine having cross-linker(e.g. allyl, vinyl groups). The chemical structure of synthesized diamine was confirmed by 1H-NMR analysis. Crosslinking profile was investigated with DSC, FT-IR spectroscopy and solubility test. Thermal crosslinking among the double bonds of polymer leads to reduction of CTE value and good chemical resistance. |
| 저자 |
장현혜1, 이주영1, 황초롱1, 박노균1, 정학기2, 원종찬1
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| 소속 |
1한국화학(연), 2코오롱인더스트리 |
| 키워드 |
polyimide; crosslink; ally-l3; 5-diaminobenzene; 6-FDA
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| E-Mail |
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