| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
분자전자 부문위원회 Ⅰ,Ⅱ |
| 제목 |
Squarylium-Based Colorimetric Probe for the rapid and selective detection of Hydrogen Sulfide |
| 초록 |
In this study, we developed a new colorimetric chemosensor (SQ1, SQ2, and SQ3) based on Squarylium for efficient H2S detection, and their detection properties were systematically characterized. SQ1 exhibited rapid and high resolution H2S sensing properties through significant color changes detectable by naked-eye with limit of detection as low as 7.2 ppb. SQ1 also showed highly selectivity for H2S detection over other relevant anions and nucleophiles. Sensing mechanisms of SQ1 were investigated based on spectroscopic and 1 H NMR analyses with quantum calculations. Furthermore, SQ1 showed an efficient response to H2S under versatile conditions in the solution, solid, and dyed fabric states, which suggests applicability of SQ1 to simple, low-cost, and practical H2S sensors |
| 저자 |
전혜원1, 노하림1, 오병민1, 박영기2, 이준엽3, 김재건3, Jian Zheng4, 정대웅3, 이우성3, 김종현1
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| 소속 |
1아주대, 2DYETEC, 3KITECH, 4Lingnan Normal Univ. |
| 키워드 |
spectroscopic characterization; colorimetric chemosensor; squarylium derivative; hydrogen sulfide; selectivity
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| E-Mail |
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