| 학회 | 한국공업화학회 |
| 학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 26권 1호 |
| 발표분야 | 포스터-촉매 |
| 제목 | Selective production of liquid-range (C5-C20) hydrocarbons from syngas using bifunctional Fe-ZSM-5 catalysts activated by CO2-containing syngas |
| 초록 | Low-temperature Fischer-Tropsch synthesis (LT-FTS: 200−280 °C) is known as a process that produces waxes with a wide distribution of C5+hydrocarbons from syngas (CO + H2). The use bifunctional catalysts that consist of LT-FTS and acidic catalysts is one of possible ways to overcome this drawback. However, the working temperature of LT-FTS catalysts is incompatible with zeolites (≥450 °C). In this study, the precipitated-iron catalysts (P-Fe) and ZSM-5 (Si/Al: 40) were physically mixed. It was found that P-Fe catalysts activated by CO2-containing syngas favor C19+ hydrocarbons. Therefore, syngas and CO2-containing syngas activation were performed at various reaction temperatures. The highest C5-C20 was 78 wt% obtained at 275 °C using P-Fe/ZSM-5 activated by CO2-containing syngas. |
| 저자 | Deviana1, 임근배2, 이현송2, 이경우2, 윤민혜2, 박진원1, 천동현2 |
| 소속 | 1연세대, 2한국에너지기술(연) |
| 키워드 | bifunctional catalysts; CO2-containing syngas activation; ZSM-5 |
