화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터)
권호 19권 1호, p.887
발표분야 촉매 및 반응공학
제목 The study on Improvement of the efficiency of dye-sensitized solar cell with mesoporous TiO2 /TiO2 nanoparticle mixed electrodes depending on mixing ratios
초록 For improve the efficiency of DSSC, the amount of dye adsorbed and lower contact resistance are necessary. To obtain larger surface area for adsorbing more dye molecules, mesoporous TiO2 (meso-TiO2) is used for DSSC, but due to the large size difference between meso-TiO2 and P25 (nano-TiO2), there is larger contact resistance. More empty space declines the transfer rate of electron between TiO2. To reduce contact resistance, addition of nano-TiO2 into meso-TiO2 electrode could reduce the contact resistance. Furthermore, added nano-TiO2s adsorb dyes, total amount of adsorbed dyes could be increased. The result is that 65wt% of meso-TiO2 with 35wt% of nano-TiO2 electrode shows the highest efficiency.  
The characterization of electrodes and DSSC was done by X-ray diffraction (XRD), N2-sorption isotherm, UV-Vis spectrometer, Scanning Electron Microscopy (SEM), Impedance measurement, solar simulator, incident photon to charge carrier efficiency (IPCE) and Diffuse Reflectance UV-Visible Spectra (DRS).  
저자 박수빈, 김명실, 김지만
소속 성균관대
키워드 dye-sensitized solar cell; mesoporous material; Titanium dioxide
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