화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2022년 봄 (04/20 ~ 04/23, 제주국제컨벤션센터)
권호 28권 1호, p.887
발표분야 [주제 4] 탄소중립(CCUS)
제목 A study on improving conversion of methane to hydrocarbons using H-radical donors
초록 Chemical conversion of methane-based gas resources is an attractive technology in terms of reducing dependence on the oil industry. This strategy could potentially lower the greenhouse effect from a carbon-neutral perspective. Non-oxidative chemistry allows the methane to be converted to hydrogen with ethylene without producing carbon dioxide. The design of a catalytic reactor is important to increase the overall energy efficiency, where coke formation should be minimized while maximizing methane conversion. The key challenge for the non-oxidative direct conversion of methane is how to improve reactor stability under operating the reaction by nearly 1,000 ℃. We hypothesize that the H-radical donor helps to initial C-H activation of methane, which boosts the reactivity.

In this presentation, we try to elucidate the effect of H-radical donors on the non-oxidative direct conversion of methane. We have optimized the reaction parameters to finely control the reaction kinetics on both the gas phase and catalytic surface.
저자 이진주, 이성우, 김용태
소속 한국화학(연)
키워드 촉매(Catalyst)
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