| 학회 |
한국화학공학회 |
| 학술대회 |
2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터) |
| 권호 |
16권 2호, p.2179 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Baeyer-Villiger Oxidation of Ketones using Molecular Oxygen withMetalloporphyrin bridged Periodic Mesoporous Organosilica |
| 초록 |
Periodic mesoporous organosilicas (PMOs) are a special type of ordered mesoporous silica in which organic moieties are integrated onto the silica framework entirely or randomly to form hybrid organic-inorganic materials. The most important feature of PMOs are that they can incorporate various organo functionalities into inorganic frameworks to form organic-inorganic hybrid materials of which diverse organofunctionalities offer broad application. However, there are no reports on metalloporphyrin in PMO materials up to now. Herein, we report on PMOs containing metalloporphyrin (Cu,Fe). These catalysts are found to be active and selective for the Baeyer-Villiger Oxidation of ketones to lactones using molecular oxygen. |
| 저자 |
정은영, 박상언
|
| 소속 |
인하대 |
| 키워드 |
Oxidation; Periodic Mesoporous Organosilica
|
| E-Mail |
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| 원문파일 |
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