화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 촉매
제목 Hydrogen production by photodecomposition of methanol water mixture using Cu-incorporated ZnO (CuxZnyO) nanoparticles
초록 This study investigated the production of hydrogen over Cu (0.1,0.5,1.0,5.0 mol-%) incorporated ZnO nanoparticles (CuxZnyO) prepared by hydrothermal treatment. XRD confirmed that Cu was inserted into the framework of ZnO. The photocurrent increased in the Cu-incorporated catalysts. The amount of hydrogen produced by the methanol water mixture decomposition was higher in the Cu-incorporated catalysts than in the ZnO catalysts. Especially, the Cu0.01Zn0.99O catalyst showed the best hydrogen production performance. In this paper, IMVS was measured to compare the lifetime of excited electrons during photo-catalytic reaction. As a result, it has been found that the lifetime of electrons is longer on a Cu-inserted ZnO catalyst than in ZnO.
저자 최수환, 이재형, 강미숙
소속 영남대
키워드 Hydrogen production; Photodecomposition of methanol water mixture; Cu-incorporated ZnO; Electron capturing
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