| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
| 권호 |
21권 1호, p.1102 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
The Calcination Effect of Hydrotalcite-like Catalyst for Hydrogenolysis of Glycerol to 1,2-Propandiol |
| 초록 |
Glycerol is obtained as a by-product in Biodiesel Synthesis and it can be converted into many value-added chemicals. One such reaction is 1,2-propanediol(1,2-PDO) obtained by hydrogenolysis of glycerol with a base catalyst. In the present work, effect of calcination is studied. The hydrotalcite-like catalysts were prepared by impregnation method and calcined at 300 ℃, 500 ℃, 900 ℃ and 1100 ℃. All prepared catalysts were characterized by N2 physisorption, XRD, SEM, TPR and TEM. Hydrogenolysis of glycerol reaction was carried out in fixed bed down flow reactor at 190 ℃, 25 bar pressure. With 900 ℃ calcined Cu/MgAl catalyst 60 % glycerol conversion with 90 % selectivity towards 1,2-PDO was observed. The results shows that the structure and metal-support properties of hydrotalcite are governed by calcination temperature. And, it affects hydrogenolysis of glycerol reaction. |
| 저자 |
이상용1, 정재선2, 양은혁2, 이승환3, 이관영4, 문동주2
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| 소속 |
1KIST / 고려대, 2KIST / UST, 3J&K Heaters, 4고려대 |
| 키워드 |
Calcination temperature; Hydrotalcite-like catalyst; Glycerol; 1; 2-Propanediol; Hydrogenolysis
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| 원문파일 |
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